Course Information
Course Title Code Semester T + P ECTS
Physical Chemistry II KIM344 6 4 + 0 6

Prerequisites None

Language Turkish
Level Bachelor's Degree
Type Compulsory
Coordinator Prof. ŞADİ ŞEN
Instructors Prof. HÜLYA ARSLAN, Assist.Prof. JÜLİDE YENER
Goals Determination and properties of mixtures will be tired to explain by several rules and thermodynamic parameters; Colligative properties will be examined ; Properties of ideal and real solutions will be rtied to explained with Henry, Raoult and Dalton's Laws together with activity and activity coefficient ; Phase diagrams will be explained in detail ; Chemical equilibrium and the factors which affect chemical equilibrium will be examined ; Partial molar properties will be explained ; Adsorption and Absorption will be examined with some examples ; Extraction concept will be examined ; Properties of Real and İdeal solutions will be explained with thermodynamic parameters ; Basic concept of electrochemistry will be explained ; As a result, It is aimed to gain mental ability for students to apply into different fields of life
Contents Definition of mixture; Explanation of Homogenous and heterogenous mixtures with examples; Concentration terms; Properties of Ideal and Real Solutions; Explanation of 2-compounds phase diagrams, Deviation from ideality by using phase diagrams; Behaviour of electrolytic and nonelectrolytic solutions; Activity and activity coefficient concept; Chemical equilibrium; Explanation of chemical equilibrium with Thermodynamic parameters; Partial molar properties; Gibbs-Duhem equation ; Chemical potential concept ; Extraction concept ; Chemical thermodynamics; Expressing the probability that chemical reaction occur with thermodynamic parameters.
Work Placement(s) Absent

Number Learning Outcomes
1 AFTER TAKİNG THIS COURSE, A STUDENT SHOULD: be able to ability for decision of solutions whether they are real or ideal ;
2 Determine miscible or immiscible liquids from phase diagrams and thermodynamic parameters under suitable conditions;
3 Know the requirements of rules and formulas to solve the problems for ideal and real systems;
4 Notice the importance of activity and activity coefficients to know real systems ;And learn to find these parameters for which ways are required;
5 Learn the deviation from ideality which factors affect ; and learn phase diagrams and various factors for which parameters are required for expressions;
6 Explain the meanings of various types of phase diagrams;
7 Understand the gas, liqui d and solid phase systems from the phase diagrams under given conditions and learn how to determine phase and component analysis of the mixture;
8 Understand chemical equilibrium what ıt means; and thermodynamic origin of equilibrium constant expressions; and dependency of unit of equilibrium constant on different concentration units;
9 Learn the calculation of molar mass of solid matters from colligative properties;
10 Learn how anesthetic and similar events occur over Desorption-Absorption mechanisms;
11 Explain degrees of freedom with Gibbs Phase rule;
12 Determine melting point of components from solid-liquid phase diagrams; eutectic point from solid-liquid phase diagrams; Understand which types of compounds are formed during mixing at given conditions;
13 See the boiling points of components from 2-components liquid-vapor phase diagrams; understand which proportions of components may cause liquid and vapor phases; understand which conditions are expected for the formation of azeotropic mixture from phase diagrams;
14 Understand the effect of electrolytic solution on conductance; Explain that conductance of solution depends on concentration; Not confuse conductance and specific conductance terms;
15 Decide which chemical reaction occur spontaneously by using thermodynamic parameters;
16 Learn to calculate some thermodynamic parameters such as enthapy of formation, Gibbs free enthalpy,entropy values and etc. of chemical reactions by using thermodynamic tables;
17 Learn the principles that electrochemistry is based on; Learn the meaning of electrode potential values for cells; Learn the meaning of Galvanic and Electrolytic cells;

Mode of Delivery Face-to-Face
Planned Learning Activities & Teaching Methods Presentation of courses by using word and power point programs; Problem solving
Assessment Methods 1 Midterm examination; 3 homework and quizes; FINAL examination



Course Content
Week Topics Study Materials
1 Mixtures, Homogenous and heterogenous mixtures, Type of concentrations, Related problems with this subject; Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
2 Thermodynamics equalities for open and closed systems Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
3 Partial molar properties, Gibbs-Duhem equation,Detrmination of partial molar properties for two component mixtures, Phase equlibrium, Gibbs Phase Rule; Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
4 Phase diagrams for one-component systems, Clasius-Clapeyron equation, Phase transitions, Critical Points; Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
5 Definitions of Adsorption and Desorption, Anesthetic mechanisms, Nernst Distribution Law; Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
6 Extraction, Solid-State extraction, Liquid-liquid extraction, Multiple-step extraction; Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
7 Mid-term exam Repeating the lecture notes
8 Explanation of Henry,Dalton and Raoult's Laws with typical examples, 2-component phase diagrams, Explanation of phase diagrams according to Raoult and Henry'Laws; Composition-Pressure phase diagrams for vapour-liquid systems; Composition-Temperature phase diagrams for vapour-liquid systems; Liquid-Vapour Equilibrium; Solid-Liquid Equilibrium; Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
9 Azeotropic mixture;2-components Liquid-Solid Phase diagrams; Formation of chemical compound ; Eutectic Transformation; Conqruent melting; Inconqruent melting; Peritectic Transformation; Phase diagrams of partially miscible and immiscible Liquids; Phase diagrams for 3-component mixtures Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
10 Definition of Colligative properties; Preezing point Depressin; Boiling point Elevation; Vapour pressure Lowering; Osmotic Pressure Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
11 Definition of Real mixtures; Activity and Activity coefficient concept for real gas mixtures; Fugacity and fugacity coefficient concept for real gas mixtures; Detrmination of fugacity, fugacity coefficient and activity coefficient with various techniques Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
12 Definition of Chemical Thermodynamics, Internal energy of reaction, Enthalpy of reaction,Enthalpy of formation, ; Realationships between internal energy and Enthalpy; Hess Law; Enthalpy changes during chemical events; Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
13 Chemical Equilibrium; La Chatelier Rule; Determination of Equilibrium constant depending on various concentration types; Chemical equilibrium at real gas mixtures;; Heterogenous Chemical Equilibrium; Explanation of spontaneous Chemical events; Entropy of reaction;Free Enthalpy of reaction; Free Internal energy of reaction; Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects
14 Basic ters at electrochemistry, Thermodynamics of electrolytic solution, Cell potential concept; Nernst equation;Principles of cells how it works, Related problems with typical cells; Conductance Studying Physical Chemistry,Analytical Chemistry,Instrumental Analysis books, Internet sites related with course subjects



Sources
Textbook Lecture notes prepared from Fizikokimya Textbook by Y.SARIKAYA especially and Mortimer's Physical Chemisrty Textbook.Especially Y.SARIKAYA's textbook will be followed.
Additional Resources 1-Physical Chemistry Robert.G.Mortimer 2-Physical Chemistry Ira N.LEVINE, McGRAW HILL International 3-Fizikokimya Prof.Dr.Yüksel SARIKAYA



Assessment System Quantity Percentage
In-Term Studies
Mid-terms 1 80
Assignments 3 20
In-Term Total 4 100
Contribution of In-Term Studies to Overall 40
Contribution of Final Exam to Overall 60
Total 100





Course's Contribution to PLO
No Key Learning Outcomes Level
1 2 3 4 5
1 Has textbooks containing current information, application tools and equipment , and advanced theoretical and practical knowledge supported by other resources in a scientific approach. x
2 Adapts and transfers the acquired knowledge to secondary education. x
3 Uses advanced institutional and practical knowledge acquired in the field. x
4 Updates the information on daily conditions. x
5 Comments on and evaluate the data by using advanced knowledge and skills acquired in the field, identifies and analyzes the current problems of technological developments, and comes up with solutions based on research and evidence. x
6 Has the ability to conceptualize the events and facts related with the field; analyze them with scientific methods and techniques. x
7 Designs and performs experiments to analyze the problems, collects data, performs analyzes and comment on the results. x
8 Carries out an advanced study related to the field independently. x
9 Takes on responsibility individually and as a team member in order to solve unpredictable and complex problems encountered in applications related to the field. x
10 Plans and manages the activities in a project under his responsibility for development. x
11 Plays a role in the process of decision making when faced with problems about different discipline fields. x
12 Uses time effectively in the process of inference with the ability of thinking analytically. x
13 Evaluates the advanced knowledge and skills acquired in the field with a critical perspective. x
14 Determines the learning requirements and leads the learning process. x
15 Develops a positive attitude towards lifelong learning. x
16 Is aware of the necessity of lifelong learning and develops his Professional knowledge and skills continuously. x
17 Informs people and organizations about the topics related to their fields; expresses his ideas and suggestions for solutions to problems in both oral and written form. x
18 Shares his ideas and suggestions for solutions to the problems with experts and non-experts by supporting them with quantitative and qualitative data. x
19 Organizes projects and activities for social environment he lives in with an awareness of social responsibility. x
20 Follows advances in the field and communicate with colleagues by using a foreign language at least at B1 level of European Language Portfolio. x
21 Uses information and communication technology along with software the Human Sciences the field requires at an advanced level. x
22 Uses his knowledge of human health and environmental awareness acquired in their fields for society’s ends. x
23 Behaves in a way adhering to the social, scientific, cultural and ethical values in the process of data collection, commenting, application, publicizing the results related with the field x
24 Has a sufficient level of awareness about the universality of social rights, social justice, quality management, acting in a suitable way in processes and attendance (Instead of quality culture) the protection of cultural values, protection of the environment and health and security in the professional field. x



ECTS ALLOCATED BASED ON STUDENT WORKLOAD BY THE COURSE DESCRIPTION
Activities Quantity Duration (Hour) Total Work Load (h)
Course Duration 14 4 56
Hours for off-the-classroom study (Pre-study, practice) 14 4 56
Assignments 3 9 27
Mid-terms 1 16 16
Final examination 1 18 18
Total Work Load (h) 173
Total Work Load / 30 (h) 5.77
ECTS Credit of the Course 6